1. Balance the following equations.

___C3H8 + ___O2 = ___CO2 + ___H2O

________ H2 + ______N2 = _______ NH3

___CaO(s) + ___H2O(l) = ____Ca+2(aq) + _____OH-(aq)

2. a) Calculate the frequency of light that has a wavelength of 562 nm. c= 3.0x108 m/s. Include units.

b) Calculate the energy of one photon of red light that has a wavelength of 562 nm. h= 6.6x10-34 J-s

.3. Calculate the oxidation state of the following underlined atoms.

a) O2

b) MnO4-

c) NH4+

d) K2Cr2O7

e) Na2O2

 

4. a) 0.75 moles of CO2 = _____ g

b) 1.7 g of CaCO3 = _____ moles

c) 4.7 L of 0.45 M NaOH = _____ moles of NaOH

d) 2 molecules of CO2 would weight _______ g

e) 3.7 x 10-24g = _____ kg

 

5. 6.45 g of Na2CO3 is dissolved in 450 mL of water.

a) What is the reaction equation that describes this process.

b) What is the molarity of Na2CO3 in this solution?

 

c) What is the formula and concentration of each solute species in this solution?

6. A compound has the composition 86.6% Pb and 13.3% O; 0.83% H. What is the empirical formula of the compound?

7. The Bohr equation for the energy states of a Hydrogen atom is:

En = -2.18x10-18/n2

a) What is the energy of an electron in an H atom with a principle quantum number 2.

b) What is the energy of an electron in an H atom with a principle quantum number 3.

 

c) If an electron in a H atom "falls" from a n = 3 state to an n= 2 state, what wavelength of light will be emitted?

8. Show logic that deBroglie used in arriving at his derivation of the Bohr assumption:

mvr = nh/2p (quantization of angular momentum.)