1. pH =3.56 [H +]= ________.
2. The equilibrium constant for the reaction: HCN(aq) = H + (aq) + CN- (aq) is 1x10-10 . Initially the system contains only HCN in the concentration of 2 M. At equilibrium:
a) If the [H +] is x, what are the [CN -] and the [HCN] equal to?
b) What is the approximate concentration of HCN?
c) Calculate the concentration of H + at equilibrium
3. What is the % ionization of chloroacetic acid in a 0.25 M solution?
Ka (Chloroacetic) = 1.4x10 -3
(answer = 7.6%)
4. Lactic acid has one acid H. A 0.1 M solution has a pH of 2.44; what is the Ka?
(answer = 1.3x10-4 )
5. Calculate the value of the equilibrium constants for the following reactions from the value of Ka=1.8x10-5 for AcOH and Kw.
a) AcO - (aq) + H + (aq) = HOAc(aq)
b) HOAc(aq) + OH- (aq) = H2O(l) + AcO- (aq)
c) AcO- (aq) + H2O(l) = AcOH(aq) + OH-
Ka of acetic acid is 1.8x10-5
6. What is the pH of a 0.56 M solution of NH3?
(answer = 11.5)