1. Are the aqueous solutions of the following acidic, basic or neutral in terms of their acidity? If they are either acidic or basic, write a reaction equation that explains this property.

a) NH3

b) NH4Cl

c) NaCN

d) NaCl

e) HNO3

f) CH3 OH ( a non electrolyte)

g) NaOH

h) AcOH

2. What is the pH of a 0.56 M solution of NaOAc?

3. What is the pH of a 0.23 M solution of NH4Cl?

 (answer = 4.95)

4. Define the following terms a)amphoteric b) hydrolysis c) strong electrolyte d) weak acid e) buffer solution

 

5. What is the pH of a solution that is .03 M in NH3 and 0.45 M in NH4 Cl? Kb of NH3 is 1.8x10 -5 .

 (answer = 8.1)

6. Calculate the value of the equilibrium constants for the following reactions from the value of Kb = 1.8x10-5 for NH3 and Kw.

a) NH4 + (aq) + OH -(aq) = NH3 (aq) + H2O(l)

b) NH4 + (aq) = H + (aq) + NH3 (aq)

c) NH3 (aq) + H + (aq) = NH4 + (aq)

 

7. Define the following terms and give an example of each using acetic acid or acetic acid derivitives.

a) hydrolysis b) strong electrolyte c) weak acid

d) buffer solution e) conjugate base of an acid

8. Calculate the % ionization of acetic acid in a 0.2 M solution of acetic acid.