1.
Define and give examples to differentiate between the terms :
rate, rate constant, rate equation, order of reaction, order from the menu,
overall order, order in a specific reaction. Given initial rates of
reaction (make them up) and concentrations, determine the orders of a reaction,
the rate equation, and the rate constant.
2. a) For
a first order reaction: give an example of the appropriate rate equation
and an integrated expression that relates concentration to time.
b) For a second order
reaction: give an example of the appropriate rate equation and an integrated
expression that relates concentration to time.
3.
How does temperature effect the rate of reaction? What equation
relates the rate constants to temperature? How is this effect
accounted for by collision theory? Demonstrate that you
know what the terms activation energy, transition state or activated
complex mean.
4.
What is the difference between a reaction equation and a mechanism
of a reaction? What is the difference between the stoicheometric coefficients
and the molecularity of a reaction step? Give an example of a couple
of mechanisms of reactions . Include the overall reaction; the
mechanism; the rate equation. Give an example of a catalyst and the
mechanism by which it operates. What is an inhibitor?