1. In the neutral species PF3 all of the F atoms are equivalent, the P-31 spectrum will consist of how many peaks in what intensity ratios?
2. In the neutral species PF3 all of the F atoms are equivalent, the F-19 spectrum will consist of how many peaks in what intensity ratios?
3. How many peaks will there be in a "normal" decoupled C-13 spectrum of n-butanol, CH3CH2CH2CH2OH?
Table of the NMR Properties of Some Isotopes
|
isotope |
I |
% abun-dance |
sensi-tivity 1 pulse |
n in MHz at 4.6 T |
|
H-1 |
1/2 |
99.98 |
1.00 |
200 |
|
H-2 |
1 |
0.015 |
.000001 |
30.7 |
|
C-13 |
1/2 |
1.11 |
.000176 |
50.3 |
|
V-51 |
7/2 |
100 |
.125 |
52.1 |
4. Classify each of the following nuclei as S-sharp if it has spin 1/2, I-inactive if it has spin 0, B-broad if it has a spin >1/2.
a) H-1
b) V-51
5. How many orientations does a nucleus of H-2 have?
6. What will the splitting pattern be of the C-13 in the CDCl3 where D = H-2 (the Cl nuclei do not split the C-13)?