1. In the neutral species PF3 all of the F atoms are equivalent, the P-31 spectrum will consist of how many peaks in what intensity ratios?


2. In the neutral species PF3 all of the F atoms are equivalent, the F-19 spectrum will consist of how many peaks in what intensity ratios?

 

3. How many peaks will there be in a "normal" decoupled C-13 spectrum of n-butanol, CH3CH2CH2CH2OH?


Table of the NMR Properties of Some Isotopes

isotope

I

% abun-dance

sensi-tivity

1 pulse

n in MHz at

4.6 T

H-1

1/2

99.98

1.00

200

H-2

1

0.015

.000001

30.7

C-13

1/2

1.11

.000176

50.3

V-51

7/2

100

.125

52.1



4.  Classify each of the following nuclei as S-sharp if it has spin 1/2,  I-inactive if it has spin 0, B-broad if it has a spin >1/2.

 

a) H-1

b) V-51

5. How many orientations does a nucleus of H-2 have? 

 

6.  What will the splitting pattern be of the C-13   in the CDCl3 where D = H-2 (the Cl nuclei do not split the C-13)?